Product ID:ARGOSHIELD GAS 5H
MSDS Date:06/18/1992
FSC:6830
NIIN:00N046577
MSDS Number: BSHGG

BOC GROUP INC

575 MOUNTAIN AVE
MURRAY HILL, NJ 07974
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 908-464-8100

Cage: HO796

BOC GROUP INC

MURRAY HILL, NJ 07974 US

Telephone: 908-464-8100

Cage: HO796

OF PROD FROM CYL. USE CHECK VALVE/TRAP IN DISCHARGE

RTECS: 9999999ZZ

PHYSICAL DMG. STORE IN COOL, DRY, WELL-VENT AREA AWAY

RTECS: 9999999ZZ

ALLOW TEMP WHERE CYL STORED TO EXCEED 125F (54C).

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FALLING/BEING KNOCKED OVER. FULL & EMPTY CYLS SHOULD

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TO PVNT FULL CYLS BEING STORED FOR EXCESSIVE PERIODS

RTECS: 9999999ZZ

STORAGE AREA/USE AREA. THERE SHOULD BE NO SOURCES OF

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COMPRESSED GAS CYL SHOULD NOT BE REFILLED EXCEPT

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OF COMPRESSED GAS CYL WHICH HAS NOT BEEN FILLED BY

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FED LAW (49CFR). NEVER CARRY COMPRESSED GAS

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AS CAR TRUNK, VAN/STATION WAGON. LEAK CAN RSLT IN

RTECS: 9999999ZZ

COMPRESSED GAS ASSOC PAMPHLETS P-1, P-9, SFTY

RTECS: 9999999ZZ

ARGON

CAS: 7440-37-1

RTECS: CF2300000

Fraction By Weight: 65-99.9%

OSHA PEL N/K

ACGIH TLV: ASPHYXIANT

7333-74-0

CAS: 1333-74-0

RTECS: MW8900000

Fraction By Weight: 0.1-35%

OSHA PEL N/K

ACGIH TLV: ASPHYXIANT

SLIDE/ROLL CNTNRS. USE SUITABLE HAND TRUCK

RTECS: 9999999ZZ

CONNECTING CYL TO LOWER PRESS (<3000 PSIG)

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HYDROGEN IN ARGON GAS MIXTURE IS
SIMPLE ASPHYXIANT. HIGH CONCENTRATIONS OF THIS GAS MIXTURE WHICH
EXCLUDE ADEQUATE SUPPLY OF OXYGEN FROM LUNGS CAUSES DIZZINESS,
DEEPER BREATHING DUE TO AIR HUNGER (ANO XIA), POSSIBLE NAUSEA &
EVENTUAL UNCONSCIOUSNESS. HYDROGEN & ARGON ARE RELATIVELY INACTIVE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:BIOLOGICALLY & ESSENTIALLY NONTOXIC;
THEREFORE, THE MAJOR HAZARD IS THE EXCLUSION OF AN ADEQUATE SUPPLY
OF OXYGEN TO THE LUNGS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:CALL MD IMMED. EYES:IMMED FLUSH W/POTABLE WATER FOR
MINIMUM OF 15 MIN, SEEK ASSISTANCE FROM MD. SKIN: FLUSH W/COPIOUS
AMTS WATER. CALL MD. INHAL:ASSIST TO UNCONTAMD AREA & INH ALE FRESH
AIR. QUICK REMOVAL FROM CONTAMD AREA IS MOST IMPORTANT. UNCON PERS
SHOULD BE MOVED TO UNCONTAMD AREA. IF NOT BRTHG ADMIN ARTF
RESUSCITATION. FURTHER TREATMENT SHOULD BE SYMPTOMATIC & (SUPDAT

Lower Limits:4% (H2)
Upper Limits:74.5% (H2)
Extinguishing Media:USE EXTING MEDIA SUITABLE FOR COMBUSTIBLE MATLS
INVOLVED IN THE FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
IF POSS, STOP FLOW OF GAS MIX. HYDROGEN BURNS W/ALMOST INVISIBLE
FLAME OF RELATIVELY LOW THERMAL (SUPDAT)
Unusual Fire/Explosion Hazard:HYDROGEN IS VERY LIGHT & RISES VERY
RAPIDLY IN AIR. SHOULD HYDROGEN GAS MIX FIRE BE EXTING & FLOW OF
GAS CONTINUE, INCR VENT TO PVNT EXPLO HAZ, ESP IN (SUPDAT)

Spill Release Procedures:EVACUATE ALL PERS FROM AFFECTED AREA. USE
APPROP PROT EQUIP. IF LEAK IS IN USER'S EQUIP, BE CERTAIN TO PURGE
PIPING W/INERT GAS PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN
CNTNR/CNTNR VALVE, CNTCT CHEM TREC FOR EMER ASSISTANCE OR YOUR
CLOSEST MFR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:USE ONLY IN WELL-VENT AREAS. VALVE
PROT CAPS MUST REMAIN IN PLACE UNLESS CNTNR IS SECURED W/VALVE
OUTLET PIPED TO USE POINT. DO NOT DRAG, (ING 3)
Other Precautions:EARTH-GROUND & BOND ALL LINES & EQUIP ASSOC
W/HYDROGEN IN ARGON GAS MIX SYS. ALL ELEC EQUIP SHOULD BE
NON-SPK/EXPLO PROOF. COMPRESSED GAS CYL SHOULD NOT BE REFILLED
EXCEPT BY QUALIFIED PRODUCERS OF CO MPRESSED GASES. SHIPMENT OF
(ING 11)

Respiratory Protection:NIOSH/MSHA APPROVED SUPPLIED AIR RESPIRATOR
W/FULL FACEPIECE EQUIPPED W/ESCAPE BOTTLE OR NIOSH/MSHA APPRVD SCBA
SHOULD BE AVAILABLE FOR EMERGENCY USE. OPERATE THIS EQUIPMENT IN
THE POSITIVE PRESSURE D EMAND MODE.
Ventilation:USE LOC EXHST & GENERAL VENT TO MAINTAIN MIN 19.5% OXYGEN
LEVEL IN AMBIENT AIR. MECH IN ACCORDANCE W/ELECTRICAL CODES.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:SAFETY GOGGLES.
Other Protective Equipment:SAFETY SHOES, SAFETY SHOWER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV:0.725 TO 1.38 (AIR=1). VAP DENS: 0.054 TO 0.103 LB/CU FT.
FIRE FIGHT PROC:RADIA. DO NOT DETECT LEAKS W/ HANDS/OPEN FLAME!
EXPLO HAZ:UPPER PORTIONS OF BLDGS/SHEDS WHERE GAS MIGHT "COLLECT."
F IRST AID PROC:SUPPORTIVE. PROMPT MED ATTENTION MANDATORY IN ALL
CASES OF OVEREXP. RESCUE PERS SHOULD WEAR SCBA.

HCC:G3
Vapor Density:SUPDAT
Spec Gravity:SUPDAT
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS GAS; ODORLESS.

Stability Indicator/Materials to Avoid:YES
CHLORINE, FLUORINE, LITHIUM METAL, TITANIUM.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF WASTE/UNUSED
QUANTITIES. RETURN IN SHIPPING CONTAINER PROPERLY LABELED, WITH ANY
VALVE OUTLET PLUGS OR CAPS SECURE & VALVE PROTECTION CAP IN PLACE
TO MFR FOR PROPER DISPOS AL.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.